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• W1973114912 abstract "Addition of [I(py)2]BF4 to Ru(CCH)(dppe)Cp∗ gave the iodovinylidene [Ru(CCHI)(dppe)Cp∗]BF4 1, which could be deprotonated to Ru(CCI)(dppe)Cp∗ 2. The attempted preparation of Ru(CCCCI)(dppe)Cp∗, followed by derivatisation with tcne, gave the dienynyl Ru{CCC[C(CN)2]CIC(CN)2}(dppe)Cp∗ 3. The Pd(0)/Cu(I)-catalysed reaction of 3 with Ru{CCCCAu(PPh3)}(dppe)Cp∗ afforded Ru{CCCC(CN)2CC(CN)2Au(PPh3)}(dppe)Cp∗ 4 by formal replacement of I+ by [Au(PPh3)]+. XRD structures of 1–4 are reported." @default.
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• W1973114912 date "2008-08-01" @default.
• W1973114912 modified "2023-09-24" @default.
• W1973114912 title "Iodo-alkynyl- and iodo-butadiynyl-ruthenium complexes" @default.
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• W1973114912 doi "https://doi.org/10.1016/j.jorganchem.2008.06.008" @default.
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