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- W1973127906 endingPage "144" @default.
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- W1973127906 abstract "Two novel sandwich-type (phthalocyaninato)(porphyrinato) europium double-decker complexes, namely Eu(Pc)[(NHC8H17)PP] (1) and Eu(Pc)[(NHC8H17)4PP] (2), have been designed and synthesized. Their self-assembly properties, in particular the effect of the numbers of octylaminophenyl groups on the morphology of self-assembled nanostructures of these double-decker complexes, have been comparatively and systematically studied. Depending mainly on the hydrogen bond between one octylaminophenyl group at meso-attached phenyl group of porphyrin ligand in 1 and one aza-nitrogen atom of the phthalocyanine ring in the neighboring molecule of 1, 1 self-assembled into nano-rods with J-type aggregation. In good contrast, introduction of four octylaminophenyl groups onto the meso-attached phenyl groups of the porphyrin ligand in 2, induces more N–H⋯N hydrogen bonds between neighboring molecules of 2, induces the formation of nano-sheets with H-type aggregation. These results clearly imply the effective influence of hydrogen bond numbers on the molecular stacking mode and the morphology of the assembled nanostructures." @default.
- W1973127906 created "2016-06-24" @default.
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- W1973127906 date "2015-02-01" @default.
- W1973127906 modified "2023-09-27" @default.
- W1973127906 title "Self-assembly of sandwich-type (phthalocyaninato)(porphyrinato) europium double-decker complexes: Effects of hydrogen bonding on intermolecular stacking mode and morphology of self-assembled nanostructures" @default.
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- W1973127906 doi "https://doi.org/10.1016/j.dyepig.2014.08.008" @default.
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