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- W1973144472 abstract "The adduct Eu(btfa)3bipy (btfa = 4,4,4-trifluoro-1-phenyl-2,4-butanedione, bipy = 2,2'-bipyridine) was synthesized and its X-ray structure was determined. The UV absorption spectra of the ligands and complex were obtained in ethanolic solution. The luminescence spectrum of the solid complex at 77 K suggests the existence of a single emitting site, in agreement to the X-ray structure. The electronic spectrum of the complex was fairly predicted via the INDO/S-CI method, using either of two input geometries: one from the X-ray data and another obtained by the SMLC/AM1 method. Finally, we have also observed that the fluorinated β-diketonates of Eu(III) adducts, like Eu(btfa)3bipy, are more luminescent than the analogous nonfluorinated ones." @default.
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- W1973144472 date "1997-06-01" @default.
- W1973144472 modified "2023-10-18" @default.
- W1973144472 title "Synthesis, crystal structure determination and theoretical prediction of the structure and electronic spectrum of Eu(btfa)3bipy" @default.
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- W1973144472 doi "https://doi.org/10.1016/s0022-2313(96)00158-5" @default.
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