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- W1973156937 abstract "Measurements of vapour pressures have been made using a static method for the binary systems of quinoline (C9H7N) with chloroform (CHCl3), methylene chloride (CH2Cl2), carbon tetrachloride (CCl4), benzene (C6H6) and cyclohexane (c-C6H12) at 293.15 K. The total pressure vs. liquid phase composition data have been used to calculate for the various systems, the activity coefficients γA and γB of C9H7N (A) and the other component (B) and the excess molar Gibbs energies, GEm, by using Barker's procedure. GEm is found to be highly positive for C9H7N–c-C6H12, slightly positive for C9H7N–CCl4 and C9H7N–C6H6, and negative for C9H7N–CHCl3 and C9H7N–CH2Cl2. GEm data at xA= 0.5 for the various systems have been used to estimate Kf, the equilibrium constant for the formation of the 1 : 1 (AB) complex, using Saroléa-Mathot's theory of associated solutions. GEm and Kf data show that C9H7N forms tight complexes with CHCl3 and CH2Cl2 owing to strong intermolecular association in the liquid state, and that it forms weak complexes with CCl4 and C6H6." @default.
- W1973156937 created "2016-06-24" @default.
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- W1973156937 date "1993-01-01" @default.
- W1973156937 modified "2023-09-26" @default.
- W1973156937 title "Thermodynamic behaviour of binary systems of quinoline with methylene chloride, chloroform, carbon tetrachloride, benzene and cyclohexane. Vapour pressures and excess molar Gibbs energies" @default.
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- W1973156937 doi "https://doi.org/10.1039/ft9938902429" @default.
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