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- W1973175364 abstract "Abstract A method for predicting isobaric binary and ternary vapor—liquid equilibrium data using only isothermal binary heat of mixing data and pure component vapor pressure data is presented. Three binary and two ternary hydrocarbon liquid mixtures were studied. The method consists of evaluating the parameters of the NRTL equation from isothermal heat of mixing data for the constituent binary pairs. These parameters are then used in the multicomponent NRTL equation to compute isobaric vapor—liquid equilibrium data for the ternary mixture. No ternary or higher order interaction terms are needed in the ternary calculations because of the nature of the NRTL equation. NRTL parameters derived from heat of mixing data at one temperature can be used to predict vapor—liquid equilibrium data at other temperatures up to the boiling temperature of the liquid mixture. For the systems studied this method predicted the composition of the vapor phase with a standard deviation ranging from 1–8% for the binary systems and from 4–12% for the ternary systems." @default.
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- W1973175364 date "1978-03-01" @default.
- W1973175364 modified "2023-09-27" @default.
- W1973175364 title "The prediction of isobaric phase equilibria for non-ideal multicomponent mixtures from heat of mixing data" @default.
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- W1973175364 doi "https://doi.org/10.1016/0040-6031(78)85109-0" @default.
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