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- W1973178511 abstract "The electron density distribution in garnets,Z3Ga5O12,Z=Nd, Sm, Gd, Tb, has been studied with single-crystal X-ray diffraction methods through scattering factor refinement procedures. TheZsite shows a variety of electron density residual distribution modes, implying contribution of thefelectrons. Residual electron density regions of 0.9–4.0e/Å3height seen for all four garnets at an interstitial site (Wyckoff position 48g) suggest coexistence of domains with alternatively oriented structural motifs within the single crystals. [CubicIa3d;a=12.5051(4) Å (Z=Nd),a=12.4361(3) Å (Z=Sm),a=12.3829 (5) Å (Z=Gd),a=12.3474(5) Å (Z=Tb), finalRafter anharmonic refinement:Z=Nd, 0.0114 (for 660 equivalent-averaged data);Z=Sm, 0.0111 (647);Z=Gd, 0.0152 (428);Z=Tb, 0.0118 (454).]" @default.
- W1973178511 created "2016-06-24" @default.
- W1973178511 creator A5046082600 @default.
- W1973178511 date "1997-09-01" @default.
- W1973178511 modified "2023-09-27" @default.
- W1973178511 title "Electron Density Study of Garnets:Z3Ga5O12;Z=Nd, Sm, Gd, Tb" @default.
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- W1973178511 doi "https://doi.org/10.1006/jssc.1997.7462" @default.
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