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• W1973183922 endingPage "1673" @default.
• W1973183922 startingPage "1667" @default.
• W1973183922 abstract "The dominant mode of binding of aqueous Pb(II) to single-crystal (0001) (C-cut) and (1−102) (R-cut) surfaces of α-Fe2O3 has been determined by grazing-incidence X-ray absorption fine structure (GI-XAFS) spectroscopy. Oligomeric Pb(II) complexes were found to bind in inner-sphere modes on both surfaces, which is in contrast with the binding of aqueous Pb(II) on α-Al2O3 (0001) surfaces, where Pb(II) was found in past GI-XAFS studies to bind in a dominantly outer-sphere mode, indicating a significant difference in reactivity of these two surfaces to Pb(II). This difference in reactivity to Pb(II) is explained on the basis of recent crystal truncation rod diffraction studies of the α-Fe2O3 and α-Al2O3 C-cut surfaces in contact with bulk water, which found major structural differences between the surfaces of these two metal oxides." @default.
• W1973183922 created "2016-06-24" @default.
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• W1973183922 date "2004-02-05" @default.
• W1973183922 modified "2023-10-16" @default.
• W1973183922 title "In Situ Grazing-Incidence Extended X-ray Absorption Fine Structure Study of Pb(II) Chemisorption on Hematite (0001) and (1-102) Surfaces" @default.
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• W1973183922 doi "https://doi.org/10.1021/la0354133" @default.
• W1973183922 hasPublicationYear "2004" @default.
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