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• W1973208514 abstract "Abstract We analyze here our observed Raman frequencies of the ν5 (174 cm−1) mode in NH4Cl close to its tricritical (P = 1.6 kbar) and the second order (P = 2.8 kbar) phase transitions. The critical behavior of the frequency shifts 1/ν (∂ν/∂T)P for this optical mode is described by a power-law with the critical exponent a. Our values of a = 0.01 (T   TC) for P = 1.6 kbar in NH4Cl are close to the values of 0.066 (=1/16) below TC and 0.125 (=1/8) above TC for the specific heat CP due to a three-dimensional Ising model. Our value of a = 0.18 (T   TC) is far from the Ising value (1/8), which can be reasonably compared with those obtained by previous workers, for the thermal expansivity αP and the specific heat CP in this crystalline system." @default.
• W1973208514 created "2016-06-24" @default.
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• W1973208514 creator A5030636931 @default.
• W1973208514 date "2006-04-01" @default.
• W1973208514 modified "2023-10-17" @default.
• W1973208514 title "Analysis of the Raman frequencies of a lattice mode in NH4Cl close to the tricritical and second order phase transitions" @default.
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• W1973208514 doi "https://doi.org/10.1016/j.chemphys.2005.10.015" @default.
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