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- W1973210275 abstract "Abstract A great variety of olefinic substrates having aromatic, carbocyclic and aliphatic olefins are effectively and selectively oxidized with oxygen-rich molybdenum(VI) complexes, namely [MoO(O2)2·2QOH] 1, [MoO(O2)(QO)2] 2, [Mo(O)2(QO)2] 3, [PPh4][MoO(O2)2(QO)] 4, [PPh4][Mo(O)2(O2)(QO)] 5 and [PPh4][Mo(O)3(QO)] 6 (QOH = 8-quinolinol) as catalyst, NaHCO3 as co-catalyst and H2O2 as the terminal oxidant, at room temperature. Catalysts 1 and 4 show unmatched yield, turnover number (TON) and turnover frequency (TOF), and hence shortest reaction time." @default.
- W1973210275 created "2016-06-24" @default.
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- W1973210275 date "2009-02-03" @default.
- W1973210275 modified "2023-09-26" @default.
- W1973210275 title "ChemInform Abstract: Unmatched Efficiency and Selectivity in the Epoxidation of Olefins with oxo-Diperoxomolybdenum(VI) Complexes as Catalysts and Hydrogen Peroxide as Terminal Oxidant." @default.
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- W1973210275 doi "https://doi.org/10.1002/chin.200905096" @default.
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