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• W1973228166 abstract "Deep blue solutions are formed by dissolving alkali tetrasulfides in aprotic, polar, organic solvents. Their spectra show three bands in the visible and the near UV - region at 16·2 × 103, 23·0 × 103, and 36·2 × 103 cm−1. The band at 16·2 × 103 cm−1. shows a weak, but well defined, vibrational fine structure at room temperature. The spacing between the subpeaks of 430 cm−1 is assigned to vibrations of the S2− ion formed by the homolytic dissociation of the S42− ion. The position of the S42− ⇄ 2S2− equilibrium has been studied in water-dimethylformamide mixtures as a function of the solvent composition and in pure DMF as a function of the ratio S:S2−. EPR investigations suggest the presence of two further sulfur radicals. It is proposed that the color of ultra-marine is also due to S2− ions." @default.
• W1973228166 created "2016-06-24" @default.
• W1973228166 creator A5017243499 @default.
• W1973228166 date "1968-12-01" @default.
• W1973228166 modified "2023-10-13" @default.
• W1973228166 title "On the nature of the blue solutions of sulfur" @default.
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• W1973228166 doi "https://doi.org/10.1016/0022-1902(68)80112-5" @default.
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