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- W1973236597 abstract "The aryl trifluoroacetates oxidatively added to a zerovalent palladium complex 2a with acyl-O bond cleavage under mild conditions to give the corresponding trans-(aryloxo)(trifluoroacetyl)palladium complexes 3a—3c. But 4-nitrophenyl trifluoroacetate reacted with 2a to yield cis-[Pd(OC6H4-4-NO2)2(PMe3)2] 3d, which was produced with C–O bond activation followed by disproportionation reaction. In contrast, benzyl trifluoroacetates reacted with the Pd(0) complex with benzyl–O bond fission to form benzyl(trifluoroacetato)palladium complexes 4a—4d. Complexes 4a—4d are in equilibrium in solutions between trans and cis isomers, with the proportion of the cis isomer increasing in polar solvents. Palladium-catalyzed carbonylation of benzyl trifluoroacetate has been achieved in the presence of benzyl alcohol and triethylamine to yield benzyl phenylacetate." @default.
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- W1973236597 date "1999-04-01" @default.
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- W1973236597 title "Oxidative Addition of Aryl and Benzyl Trifluoroacetates to Zerovalent Palladium Complexes with Two Modes of C–O Bond Cleavage Processes" @default.
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- W1973236597 doi "https://doi.org/10.1246/bcsj.72.799" @default.
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