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- W1973254502 abstract "Irradiation of an oxygen-free benzene solution of cis-4-flavanol 1a by a mercury lamp in the presence of benzophenone gave 4-flavanone (32%), benzopinacol (85%), cis- and trans-2-(diphenylhydroxymethyl)-4-flavanols (7.6%), and 2-(diphenylhydroxymethyl)-4-flavanone (7.7%), whereas photolysis of cis-4-acetoxyflavane under similar conditions gave cis-2-(diphenylhydroxymethyl)-4-acetoxyflavane(24%), 2,2′-bi-4-acetoxyflavane (6%), and benzopinacol. Photolysis of 1a in acetone gave 4-flavanone (3.6%), trans-4-(1-hydroxy-1-methylethyl)-4-flavanols (9.9%). The cis isomers of the parent and substituted 4-flavanols showed higher reactivities than the corresponding trans isomers." @default.
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- W1973254502 date "1977-05-01" @default.
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- W1973254502 title "Photochemical Reactions of 4-Flavanols in the Presence of Ketone Sensitizers" @default.
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- W1973254502 doi "https://doi.org/10.1246/bcsj.50.1169" @default.
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