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- W1973281981 abstract "A simple co-precipitation method was employed to synthesize a series of cubic zinc-blende phase of ZnxCd1−xS photocatalysts using Na2S as the S source. Structural, morphological and optical properties of the samples have been investigated by XRD, SEM, EDS, XRF, ICP, N2 physisorption and UV–vis diffuse reflectance techniques. The ZnxCd1−xS solid solution is not a simple compound mixture of ZnS and CdS, its XRD patterns show new structural peaks instead of mixture of original peaks. The lattice parameter a measured from the XRD patterns of the ZnxCd1−xS samples exhibits a slightly nonlinear relationship with the Zn mole fraction, which is slightly inconsistent with Vegard's law, thus suggesting that a nonhomogeneous alloy structure exists in ZnxCd1−xS solid solution. The photocatalytic H2 evolution from water splitting in the sacrificial reagents of 0.25 M Na2S/0.35 M K2SO3 under visible light at 30 °C and 55 °C were also examined in the study. It is found that ZnxCd1−xS solid solution with composition x = 0.4–0.5 shows the highest photocatalytic H2 production performance. The studied ZnxCd1−xS exhibits at least 50 h stable photocatalytic activity under outdoor sunlight irradiation." @default.
- W1973281981 created "2016-06-24" @default.
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- W1973281981 date "2014-01-01" @default.
- W1973281981 modified "2023-10-17" @default.
- W1973281981 title "Efficient and stable photocatalytic hydrogen production from water splitting over ZnxCd1–xS solid solutions under visible light irradiation" @default.
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- W1973281981 doi "https://doi.org/10.1016/j.ijhydene.2013.11.059" @default.
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