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• W1973287007 abstract "In poly[[μ 3 -2,2′-(disulfanediyl)dibenzoato-κ 5 O : O , O ′: O ′′, O ′′′](1,10-phenanthroline-κ 2 N , N ′)cadmium(II)], [Cd(C 14 H 8 O 4 S 2 )(C 12 H 8 N 2 )] n , the asymmetric unit contains one Cd II cation, one 2,2′-(disulfanediyl)dibenzoate anion (denoted dtdb 2− ) and one 1,10-phenanthroline ligand (denoted phen). Each Cd II centre is seven-coordinated by five O atoms of bridging/chelating carboxylate groups from three dtdb 2− ligands and by two N atoms from one phen ligand, forming a distorted pentagonal–bipyramidal geometry. The Cd II cations are bridged by dtdb 2− anions to give a two-dimensional (4,4) layer. The layers are stacked to generate a three-dimensional supramolecular architecture via a combination of aromatic C—H...π and π–π interactions. The thermogravimetric and luminescence properties of this compound were also investigated." @default.
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• W1973287007 date "2014-04-30" @default.
• W1973287007 modified "2023-09-27" @default.
• W1973287007 title "A two-dimensional CdII coordination polymer with 2,2′-(disulfanediyl)dibenzoate and 1,10-phenanthroline ligands" @default.
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• W1973287007 doi "https://doi.org/10.1107/s2053229614009036" @default.
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