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- W1973292241 abstract "As part of our systematic study on the curing reaction of novolac resins with hexamethylenetetramine (HMTA), the reactions between 2,6-xylenol (a model phenol) and HMTA, and the thermal decomposition of their first-formed products bis- and tris(4-hydroxy-3,5-dimethylbenzyl)amines have been studied by13C and15N n.m.r. spectroscopy. The thermal decomposition of bis- and tris(4-hydroxy-3,5-dimethylbenzyl)amines results in the formation of para—para methylene linkages between phenolic rings. Other products are formed during the process, and only minor amounts of these remain after heating to 205°C/4 h; however, these minor products provide important information on the reaction pathways. The possible reaction mechanisms/pathways for the formation of cross-linked networks from para-hydroxybenzylamine intermediates are postulated on the basis of these structural changes." @default.
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- W1973292241 date "1998-05-01" @default.
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- W1973292241 title "The chemistry of novolac resins: Part 7. Reactions of para-hydroxybenzylamine intermediates" @default.
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- W1973292241 doi "https://doi.org/10.1016/s0032-3861(97)00466-7" @default.
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