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- W1973313798 abstract "Abstract The observation that the syn ‐isomer 1 of 1,4:5,8‐diepoxy‐1,4,5,8‐tetrahydroanthracene becomes involved in a series of highly diastereoselective Diels‐Alder reactions with 2,3,5,6‐tetramethylene‐7‐oxabicyclo[2.2.1]heptane 2 to form, in excellent overall yield, the novel macropolycyclic compound 6 ‐ a potential precursor of [12]beltene 7 , [12]collarene 8 , [12]cyclacene 9 , and the perhydro[12]cyclacene derivative 10 ‐ is interpreted in terms of the stereoelectronic characteristics of the dienophilic components of 1 and the diene components of 2 , and obvious steric factors, combining to favour one particular stereochemistry out of eight possibilities for the transition states involving each of the four different cycloaddition steps." @default.
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- W1973313798 date "1988-01-01" @default.
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- W1973313798 title "Stereoelectronically‐programmed molecular ‘lego’ sets" @default.
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- W1973313798 doi "https://doi.org/10.1002/bscb.19880970807" @default.
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