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- W1973347622 abstract "Durch Umsetzung von N-Benzoylthiocarbamid-O,S-diethylester mit primären Diaminen wurden (oxa)alkylen-verbrückte Isoharnstoffe 1 erhalten. Diese bilden mit CuII mononukleare Neutralchelate 2 mit tetradentater Ligandkoordination. Die Strukturen des Liganden 1 a und des zugehörigen CuII-Komplexes 2 a wurden röntgenographisch bestimmt. Sie zeigen eine Enamin-Tautomerie im Liganden und eine leicht tetraedrisch verzerrte Koordination mit einer Oxaalkylen-Brücke zwischen den trans-ständigen N-Ligatoratomen im Komplex. Mononuclear Copper(II) Complexes of Dioxaalkylene and Alkylene Bridged Bis-isoureas By reaction of N-benzoylthiocarbamic-O,S-diethylester with primary diamines (oxa)alkylene bridged isoureas 1 have been prepared. They yield with CuII neutral chelates 2 with tetradentate ligand coordination. The structures of the ligand 1 a and of the related CuII complex 2 a have been determined by X-ray crystal structure analysis. They show an enamine tautomer in the ligand and a slightly tetrahedrally distorted coordination with an (oxa)alkylene bridge between the trans arranged N ligator atoms in the complex." @default.
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- W1973347622 date "2001-08-01" @default.
- W1973347622 modified "2023-09-23" @default.
- W1973347622 title "Mononukleare Kupfer(II)-Komplexe von dioxaalkylenund alkylenverbrückten Bis-isoharnstoffen" @default.
- W1973347622 doi "https://doi.org/10.1002/1521-3749(200108)627:8<1877::aid-zaac1877>3.0.co;2-x" @default.
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