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• W1973376589 abstract "Powerful reductants [Os(II)(NH(3))(5)L](2+) (L = OH(2), CH(3)CN) can be generated upon ultraviolet excitation of relatively inert [Os(II)(NH(3))(5)(N(2))](2+) in aqueous and acetonitrile solutions. Reactions of photogenerated Os(II) complexes with methyl viologen to form methyl viologen radical cation and [Os(III)(NH(3))(5)L](3+) were monitored by transient absorption spectroscopy. Rate constants range from 4.9 × 10(4) M(-1) s(-1) in acetonitrile solution to 3.2 × 10(7) (pH 3) and 2.5 × 10(8) M(-1) s(-1) (pH 12) in aqueous media. Photogeneration of five-coordinate Os(II) complexes opens the way for mechanistic investigations of activation/reduction of CO(2) and other relatively inert molecules." @default.
• W1973376589 created "2016-06-24" @default.
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• W1973376589 date "2011-01-01" @default.
• W1973376589 modified "2023-10-14" @default.
• W1973376589 title "Redox reactivity of photogenerated osmium(ii) complexes" @default.
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• W1973376589 doi "https://doi.org/10.1039/c1dt11138h" @default.
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