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- W1973403606 abstract "α-d-Galactosidase, isolated from germinating seeds of guar, removed up to 48% of the (1 → 2)-linked α-d-galactose side chains of Rhizobium capsular polysaccharide (CPS), with no loss of the disaccharide side chains (1 → 6)-linked to the same backbone residues in the hexasaccharide repeating units. Results from differential scanning calorimetry (DSC) and measurements of gel rigidity (G′) indicate that removal of α-d-galactose side chains facilitates adoption of the “pseudo double-helical” structure proposed from X-ray fibre diffraction analysis (increase in Tm and reduction in DSC peak width for conformational ordering on cooling), but progressively eliminates the helix-helix aggregation necessary for gel formation (reduction in thermal hysteresis and in G′)." @default.
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- W1973403606 date "1992-07-01" @default.
- W1973403606 modified "2023-09-30" @default.
- W1973403606 title "Selective removal of α-d-galactose side chains from Rhizobium capsular polysaccharide by guar α-d-galactosidase: effect on conformational stability and gelation" @default.
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- W1973403606 doi "https://doi.org/10.1016/0008-6215(92)84018-n" @default.
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