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- W1973407841 abstract "The nitrosylcarbonyl cluster [Ir6(CO)14NO]− has been prepared by one-electron oxidation of [Ir6(CO)15]2−, followed by addition of NO at low temperature. The structure of the salt [NMe3(CH2Ph)][Ir6(CO)11(μ-CO)3NO] was solved by direct methods and difference Fourier techniques and refined down to R = 0.036, for 3239 observed reflections having I > 3σ(I). The cluster of idealized Cs point group symmetry contains an octahedral metal framework of iridium atoms, an NO group linearly bound, which acts as a three-electron donor, 11 terminal and three edge-bridging carbonyl ligands. The IrN separation of 1.75(3) Å is the shortest metal-to-ligand bond distance. Average distances are: IrIr = 2.773 Å, IrCterm = 1.86 Å, Cterm −Oterm = 1.16 Å, IrCbridg = 2.02 Å, Cbridg−Obridg = 1.19 Å." @default.
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- W1973407841 date "1995-02-01" @default.
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- W1973407841 title "Octahedral iridium carbonyl clusters. Synthesis, characterization and solid state structure of the nitrosyl cluster [Ir6(CO)11(μ-CO)3NO]−" @default.
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- W1973407841 doi "https://doi.org/10.1016/0022-328x(94)00022-5" @default.
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