FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1973441536> ?p ?o ?g. }

• W1973441536 endingPage "11504" @default.
• W1973441536 startingPage "11491" @default.
• W1973441536 abstract "The tritopic bridging ligand hexaazatriphenylene (HAT) has been used to prepare the mono-, di-, and trinuclear cyanoruthenate complexes [Ru(CN)4(HAT)]2- ([1]2-), [{Ru(CN)4}2(μ2-HAT)]4- ([2]4-), and [{Ru(CN)4}3(μ3-HAT)]6- ([3]6-). These complexes are of interest both for their photophysical properties and ability to act as sensitizers, associated with strong MLCT absorptions; and their structural properties, with up to 12 externally directed cyanide ligands at a single “node” for preparation of coordination networks. The complexes are strongly solvatochromic, with broad and intense MLCT absorption manifolds arising from the presence of low-lying π* orbitals on the HAT ligand, as confirmed by DFT calculations; in aprotic solvents [3]6- is a panchromatic absorber of visible light. Although nonluminescent in fluid solution, the lowest MLCT excited states have lifetimes in D2O of tens of nanoseconds and could be detected by time-resolved IR spectrosocopy. For dinuclear [2]4- and trinuclear [3]6- the TRIR spectra are indicative of asymmetric MLCT excited states containing distinct Ru(III) and Ru(II) centers on the IR time scale. The complexes show red 3MLCT luminescence as solids and in EtOH/MeOH glass at 77 K. Ln(III) salts of [1]2-, [2]4-, and [3]6- form infinite coordination networks based on Ru−CN−Ln bridges with a range of one-, two-, and three-dimensional polymeric structures. In the Yb(III) and Nd(III) salts of [3]6- the complex anion forms an 8-connected node. Whereas all of the Gd(III) salts show strong 3MLCT luminescence in the solid state, the Ru-based emission in the Nd(III) and Yb(III) analogues is substantially quenched by Ru → Ln photoinduced energy transfer, which results in sensitized near-infrared luminescence from Yb(III) and Nd(III)." @default.
• W1973441536 created "2016-06-24" @default.
• W1973441536 creator A5019424138 @default.
• W1973441536 creator A5029701197 @default.
• W1973441536 creator A5034915235 @default.
• W1973441536 creator A5040483527 @default.
• W1973441536 creator A5056361445 @default.
• W1973441536 creator A5073978252 @default.
• W1973441536 creator A5074807639 @default.
• W1973441536 creator A5079302315 @default.
• W1973441536 creator A5083477448 @default.
• W1973441536 creator A5085420168 @default.
• W1973441536 date "2007-08-22" @default.
• W1973441536 modified "2023-10-02" @default.
• W1973441536 title "Photophysical and Structural Properties of Cyanoruthenate Complexes of Hexaazatriphenylene" @default.
• W1973441536 cites W1963866364 @default.
• W1973441536 cites W1964031104 @default.
• W1973441536 cites W1971032755 @default.
• W1973441536 cites W1974852612 @default.
• W1973441536 cites W1975180160 @default.
• W1973441536 cites W1978744616 @default.
• W1973441536 cites W1982090792 @default.
• W1973441536 cites W1984576643 @default.
• W1973441536 cites W1984955148 @default.
• W1973441536 cites W1986017040 @default.
• W1973441536 cites W1986555850 @default.
• W1973441536 cites W1992150952 @default.
• W1973441536 cites W1992982961 @default.
• W1973441536 cites W1995042715 @default.
• W1973441536 cites W1995542857 @default.
• W1973441536 cites W1996921125 @default.
• W1973441536 cites W1998270541 @default.
• W1973441536 cites W1998661255 @default.
• W1973441536 cites W1998993432 @default.
• W1973441536 cites W1999713384 @default.
• W1973441536 cites W2001177502 @default.
• W1973441536 cites W2004761305 @default.
• W1973441536 cites W2007891536 @default.
• W1973441536 cites W2015581546 @default.
• W1973441536 cites W2016173822 @default.
• W1973441536 cites W2019602992 @default.
• W1973441536 cites W2021502908 @default.
• W1973441536 cites W2033050479 @default.
• W1973441536 cites W2034706873 @default.
• W1973441536 cites W2038358840 @default.
• W1973441536 cites W2044961513 @default.
• W1973441536 cites W2046112013 @default.
• W1973441536 cites W2050056663 @default.
• W1973441536 cites W2054202089 @default.
• W1973441536 cites W2055727254 @default.
• W1973441536 cites W2065888656 @default.
• W1973441536 cites W2067299781 @default.
• W1973441536 cites W2067713373 @default.
• W1973441536 cites W2068228867 @default.
• W1973441536 cites W2069197437 @default.
• W1973441536 cites W2069969127 @default.
• W1973441536 cites W2071503022 @default.
• W1973441536 cites W2072037294 @default.
• W1973441536 cites W2073886079 @default.
• W1973441536 cites W2074978114 @default.
• W1973441536 cites W2078211938 @default.
• W1973441536 cites W2080078031 @default.
• W1973441536 cites W2081825058 @default.
• W1973441536 cites W2082374231 @default.
• W1973441536 cites W2086433642 @default.
• W1973441536 cites W2088553109 @default.
• W1973441536 cites W2093075487 @default.
• W1973441536 cites W2104777257 @default.
• W1973441536 cites W2115610894 @default.
• W1973441536 cites W2120085385 @default.
• W1973441536 cites W2124574152 @default.
• W1973441536 cites W2143981217 @default.
• W1973441536 cites W2148194905 @default.
• W1973441536 cites W2156328797 @default.
• W1973441536 cites W2157026532 @default.
• W1973441536 cites W2160765180 @default.
• W1973441536 cites W2164188036 @default.
• W1973441536 cites W2171240590 @default.
• W1973441536 cites W2411648892 @default.
• W1973441536 doi "https://doi.org/10.1021/ja072672w" @default.
• W1973441536 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17713906" @default.
• W1973441536 hasPublicationYear "2007" @default.
• W1973441536 type Work @default.
• W1973441536 sameAs 1973441536 @default.
• W1973441536 citedByCount "66" @default.
• W1973441536 countsByYear W19734415362012 @default.
• W1973441536 countsByYear W19734415362013 @default.
• W1973441536 countsByYear W19734415362014 @default.
• W1973441536 countsByYear W19734415362015 @default.
• W1973441536 countsByYear W19734415362016 @default.
• W1973441536 countsByYear W19734415362017 @default.
• W1973441536 countsByYear W19734415362018 @default.
• W1973441536 countsByYear W19734415362019 @default.
• W1973441536 countsByYear W19734415362020 @default.
• W1973441536 countsByYear W19734415362021 @default.
• W1973441536 countsByYear W19734415362022 @default.
• W1973441536 countsByYear W19734415362023 @default.
• W1973441536 crossrefType "journal-article" @default.

• next