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- W1973449872 abstract "Abstract The kinetics of the aqueous polymerization of acrylonitrile initiated by the chromic acid-1-propanol redox system was investigated under a nitrogen atmosphere. The rates of polymerization and the disappearance of Cr(VI) were measured. Chromic acid alone did not initiate the polymerization under deaerated and undeaerated conditions. Water-miscible organic solvents and neutral salts depress both the rate and the conversion. On the basis of the experimental observations of the dependence of the rate of polymerization Rp and the rate of disappearance of Cr(VI)-Rm on various variables, a suitable kinetic scheme was proposed and various rate and energy parameters evaluated." @default.
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- W1973449872 date "1976-10-01" @default.
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- W1973449872 title "Redox Polymerization of Acrylonitrile: Kinetics of the Reaction Initiated by the Redox System 1-Propanol—Chromic Acid" @default.
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- W1973449872 doi "https://doi.org/10.1080/00222337608060753" @default.
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