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- W1973451339 abstract "Abstract The influence of carbon dioxide (CO2) was studied on the production of non-volatile bromine-containing residues when grains were fumigated with methyl bromide (MeBr). The residue formed on wheat at 25°C and 55% r.h., 24 hr exposure, was approximately linearly related to MeBr concentration, with a slight dependence on both the square of MeBr concentration and concentration of CO2. The latter gave a relative decrease in bromine residue of about 2.5% at 60 gm−3MeBr. Similar decreases caused by the presence of CO2 were observed under a range of moisture contents, of temperature and of exposure period. The change of rate of formation of residue with temperature corresponded to an energy of 38 MJ kg mol−1, both without CO2 or with 70% CO2 present. The effect of CO2 on residue formation was too small to be significant in practice. No effect was detected in a limited study on maize, rice, barley and sorghum. It is concluded that the reduction in residues reported when MeBr CO 2 mixtures are used in place of MeBr alone arises from changes in procedure and gas distribution not from changes in reactivity with the commodity." @default.
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- W1973451339 date "1987-04-01" @default.
- W1973451339 modified "2023-10-14" @default.
- W1973451339 title "Bromine-containing residues resulting from fumigation of grain with methyl bromide-carbon dioxide mixtures" @default.
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- W1973451339 doi "https://doi.org/10.1016/0022-474x(87)90024-5" @default.
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