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- W1973451657 abstract "A new route to α-alkyl-α-fluoromethylenebisphosphonates, 2 has been developed starting from commercially available tetraethyl fluoromethylenebisphosphonate (1), and alkyl halides using either caesium carbonate in DMF or sodium dimsyl. De-esterification of 2 provided biologically important α-alkyl-α-fluoromethylenebisphosphonic acid, 3, while alkoxide–induced carbon–phosphorus bond cleavage of 2 gave α-fluorophosphonates, 4, which are useful synthons in organic synthesis." @default.
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- W1973451657 date "2011-01-01" @default.
- W1973451657 modified "2023-10-18" @default.
- W1973451657 title "A new route to α-alkyl-α-fluoromethylenebisphosphonates" @default.
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- W1973451657 doi "https://doi.org/10.1039/c1ob05095h" @default.
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