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• W1973457046 abstract "Electrospun anatase-phase TiO2 nanofibers with desired morphological structure and relatively high specific surface area are expected to outperform other nanostructures (e.g., powder and film) of TiO2 for various applications (particularly dye-sensitized solar cell and photo-catalysis). In this study, systematic investigations were carried out to prepare and characterize electrospun anatase-phase TiO2 nanofibers with different morphological structures (e.g., solid, hollow/tubular, and porous) and specific surface areas. The TiO2 nanofibers were generally prepared via electrospinning of precursor nanofibers followed by pyrolysis at 500°C. For making hollow/tubular TiO2 nanofibers, the technique of co-axial electrospinning was utilized; while for making porous TiO2 nanofibers, the etching treatment in NaOH aqueous solution was adopted. The results indicated that the hollow/tubular TiO2 nanofibers (with diameters of ~300-500 nm and wall-thickness in the range from tens of nanometers to ~200 nm) had the BET specific surface area of ~27.3 m(2)/g, which was approximately twice as that of the solid TiO2 nanofibers (~15.2 m(2)/g) with diameters of ~200-300 nm and lengths of at least tens of microns. Porous TiO2 nanofibers made from the precursor of Al2O3/TiO2 composite nanofibers had the BET specific surface area of ~106.5 m(2)/g, whereas porous TiO2 nanofibers made from the precursor of ZnO/TiO2 composite nanofibers had the highest BET specific surface area of ~148.6 m(2)/g." @default.
• W1973457046 created "2016-06-24" @default.
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• W1973457046 date "2013-05-01" @default.
• W1973457046 modified "2023-09-28" @default.
• W1973457046 title "Electrospun anatase-phase TiO2 nanofibers with different morphological structures and specific surface areas" @default.
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• W1973457046 doi "https://doi.org/10.1016/j.jcis.2013.02.009" @default.
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