FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1973469744> ?p ?o ?g. }

• W1973469744 endingPage "957" @default.
• W1973469744 startingPage "950" @default.
• W1973469744 abstract "An evaluation and critical comparison of the performance of a reference sequential mass analyzer (quadrupole) and a ICP-TOFMS instrument for ICP-MS multielemental analysis in different types of transient signals, mimicking those encountered in speciation analysis, is described. Several parameters including integration time, the number of isotopes “simultaneously” monitored, detection limits, precision and accuracy attainable for multiisotopic ratios measurements in transient signals are critically evaluated. Multielemental measurements in typical speciation analysis transient signals of different widths at half peak heights: 26 s (similar to those obtained with HPLC separations); 8 s (alike to those obtained in fast HPLC separations); and 3.5 s (mimicking those obtained in CE separations) have been performed. As expected, the analytical performance is bound to the concentration levels and number of isotopes to be measured. The best precisions were achieved using a TOF mass analyzer (≤ 1%) for more than 15 isotopes at concentration levels over 10 ppb to be measured in transient signals of less than 5 s. However, when fewer isotopes had to be measured (less than 7), even for very short transient signals (3.5 s of fwhm), the measured precision was always similar or even better using a quadrupole mass analyzer. The detection limits obtained (even for very short integration times) were always favourable to the quadrupole ICP-MS, while ICP-TOFMS demonstrated similar or better accuracy for isotope ratio measurements. Finally, the comparative speciation analysis of a mixture of organometallics of mercury, lead and tin by GC-ICP-MS (0.7s fwhm) is also investigated and applications to real speciation problems are discussed." @default.
• W1973469744 created "2016-06-24" @default.
• W1973469744 creator A5006274229 @default.
• W1973469744 creator A5008467680 @default.
• W1973469744 creator A5089958871 @default.
• W1973469744 date "2002-01-01" @default.
• W1973469744 modified "2023-09-24" @default.
• W1973469744 title "Critical comparison between quadrupole and time-of-flight inductively coupled plasma mass spectrometers for isotope ratio measurements in elemental speciation" @default.
• W1973469744 cites W1863744829 @default.
• W1973469744 cites W1893474487 @default.
• W1973469744 cites W1968466445 @default.
• W1973469744 cites W1996572939 @default.
• W1973469744 cites W2003200787 @default.
• W1973469744 cites W2006112507 @default.
• W1973469744 cites W2008305800 @default.
• W1973469744 cites W2012851061 @default.
• W1973469744 cites W2012896267 @default.
• W1973469744 cites W2016604413 @default.
• W1973469744 cites W2032832593 @default.
• W1973469744 cites W2037648071 @default.
• W1973469744 cites W2037969080 @default.
• W1973469744 cites W2041836048 @default.
• W1973469744 cites W2042532056 @default.
• W1973469744 cites W2051724344 @default.
• W1973469744 cites W2060268720 @default.
• W1973469744 cites W2062180483 @default.
• W1973469744 cites W2076346228 @default.
• W1973469744 cites W2077323947 @default.
• W1973469744 cites W2086030818 @default.
• W1973469744 cites W2089373670 @default.
• W1973469744 cites W2090146084 @default.
• W1973469744 cites W2110045003 @default.
• W1973469744 cites W2136730436 @default.
• W1973469744 cites W2137137378 @default.
• W1973469744 cites W2145481536 @default.
• W1973469744 cites W2156963641 @default.
• W1973469744 cites W2160783170 @default.
• W1973469744 doi "https://doi.org/10.1039/b202748h" @default.
• W1973469744 hasPublicationYear "2002" @default.
• W1973469744 type Work @default.
• W1973469744 sameAs 1973469744 @default.
• W1973469744 citedByCount "34" @default.
• W1973469744 countsByYear W19734697442012 @default.
• W1973469744 countsByYear W19734697442013 @default.
• W1973469744 countsByYear W19734697442014 @default.
• W1973469744 countsByYear W19734697442019 @default.
• W1973469744 countsByYear W19734697442021 @default.
• W1973469744 countsByYear W19734697442023 @default.
• W1973469744 crossrefType "journal-article" @default.
• W1973469744 hasAuthorship W1973469744A5006274229 @default.
• W1973469744 hasAuthorship W1973469744A5008467680 @default.
• W1973469744 hasAuthorship W1973469744A5089958871 @default.
• W1973469744 hasConcept C103232671 @default.
• W1973469744 hasConcept C108649604 @default.
• W1973469744 hasConcept C113196181 @default.
• W1973469744 hasConcept C119128265 @default.
• W1973469744 hasConcept C120665830 @default.
• W1973469744 hasConcept C121332964 @default.
• W1973469744 hasConcept C158007255 @default.
• W1973469744 hasConcept C162356407 @default.
• W1973469744 hasConcept C164304813 @default.
• W1973469744 hasConcept C165697059 @default.
• W1973469744 hasConcept C184779094 @default.
• W1973469744 hasConcept C185544564 @default.
• W1973469744 hasConcept C185592680 @default.
• W1973469744 hasConcept C192562407 @default.
• W1973469744 hasConcept C39984356 @default.
• W1973469744 hasConcept C43617362 @default.
• W1973469744 hasConcept C49040817 @default.
• W1973469744 hasConcept C82706917 @default.
• W1973469744 hasConcept C95974651 @default.
• W1973469744 hasConceptScore W1973469744C103232671 @default.
• W1973469744 hasConceptScore W1973469744C108649604 @default.
• W1973469744 hasConceptScore W1973469744C113196181 @default.
• W1973469744 hasConceptScore W1973469744C119128265 @default.
• W1973469744 hasConceptScore W1973469744C120665830 @default.
• W1973469744 hasConceptScore W1973469744C121332964 @default.
• W1973469744 hasConceptScore W1973469744C158007255 @default.
• W1973469744 hasConceptScore W1973469744C162356407 @default.
• W1973469744 hasConceptScore W1973469744C164304813 @default.
• W1973469744 hasConceptScore W1973469744C165697059 @default.
• W1973469744 hasConceptScore W1973469744C184779094 @default.
• W1973469744 hasConceptScore W1973469744C185544564 @default.
• W1973469744 hasConceptScore W1973469744C185592680 @default.
• W1973469744 hasConceptScore W1973469744C192562407 @default.
• W1973469744 hasConceptScore W1973469744C39984356 @default.
• W1973469744 hasConceptScore W1973469744C43617362 @default.
• W1973469744 hasConceptScore W1973469744C49040817 @default.
• W1973469744 hasConceptScore W1973469744C82706917 @default.
• W1973469744 hasConceptScore W1973469744C95974651 @default.
• W1973469744 hasIssue "8" @default.
• W1973469744 hasLocation W19734697441 @default.
• W1973469744 hasOpenAccess W1973469744 @default.
• W1973469744 hasPrimaryLocation W19734697441 @default.
• W1973469744 hasRelatedWork W1562390349 @default.
• W1973469744 hasRelatedWork W1972707305 @default.
• W1973469744 hasRelatedWork W1973469744 @default.
• W1973469744 hasRelatedWork W1998265335 @default.

• next