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- W1973480309 abstract "Abstract The oxidations in air of epoxidized natural rubber (ENR) and its hydrobrominated product were studied and compared with the case of natural rubber (NR). By following the i.r. characteristic bands at 580, 840, 870, 1720, 1760 and 3200–3600 cm−1 during the oxidation, it was demonstrated that the hydrobrominated product of ENR is the most unstable both at room temperature and at 150°. NR oxidizes more quickly and to a greater extent than ENR. The oxidation proceeds through consumption of double bonds, leading to the formation of new oxygen-containing functional groups (hydroperoxide, hydroxyl, carbonyl, carboxyl…), changing the structure and properties of the materials. The absence of associated hydroxyl groups in the OH spectral region of hydrobrominated ENR products of low epoxide contents suggests the presence of randomly distributed epoxide groups in the polymer and indicates the random character of the epoxidation process of NR in latex." @default.
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- W1973480309 date "1990-01-01" @default.
- W1973480309 modified "2023-10-18" @default.
- W1973480309 title "Oxidation of natural rubber and its derivatives prepared by epoxidation and subsequent hydrobromination" @default.
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- W1973480309 doi "https://doi.org/10.1016/0014-3057(90)90002-l" @default.
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