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• W1973481567 abstract "Abstract Nanocrystalline titanium dioxide/carbon composite (TiO 2 /C) was synthesized through a direct solution-phase carburization using tetrabutyl titanate (Ti(OBu) 4 ) and resol as precursors. The prepared TiO 2 /C composite was mainly in the anatase structure with an average particle size under 20 nm, which was then introduced in NaAlH 4 as a catalyst through ball milling. The desorption curves show that both nanocrystalline TiO 2 /C and TiO 2 can obviously improve the kinetics of NaAlH 4 , while NaAlH 4 with 3 mol% TiO 2 /C exhibits better cycling stability than NaAlH 4 with 3 mol%TiO 2 . The hydrogen storage capacity of NaAlH 4 with TiO 2 /C remains stable after 5th cycle, and about 94% of initial hydrogen is released, while the capacity of NaAlH 4 with TiO 2 decreases continuously during cycling, and only 88% of initial hydrogen is released after 10th cycle. Furthermore, NaAlH 4 with 3 mol%TiO 2 /C exhibits good reversibility at relatively low hydrogen pressures, and it can reload 4.16 and 1.63wt% hydrogen at 50 and 30 bar hydrogen pressures, respectively." @default.
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• W1973481567 date "2011-12-01" @default.
• W1973481567 modified "2023-09-27" @default.
• W1973481567 title "Direct synthesis of nanocrystalline titanium dioxide/carbon composite and its catalytic effect on NaAlH4 for hydrogen storage" @default.
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• W1973481567 doi "https://doi.org/10.1016/j.ijhydene.2011.08.091" @default.
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