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• W1973485268 abstract "A density functional study of the experimentally observed ligand-protected gold alloy clusters PdAu12(PR3)8Cl4 and PtAu6Ag6(AgI3)2(PR3)6 reveal the same stabilization mechanism as in ligand protected pure AuN: the delocalized s-electron subsystem of a high symmetry metal core exhibits a shell closing. On the basis of this observation it is predicted that the substitution of a single Au atom in the well-known Au25(SR)18 compound with Pd, Ag, and Cd will produce stable clusters resulting in a method to tune redox properties in such a nanoscale building block." @default.
• W1973485268 created "2016-06-24" @default.
• W1973485268 creator A5008194188 @default.
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• W1973485268 date "2009-08-17" @default.
• W1973485268 modified "2023-09-23" @default.
• W1973485268 title "Ligand-Protected Gold Alloy Clusters: Doping the Superatom" @default.
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• W1973485268 doi "https://doi.org/10.1021/jp9023298" @default.
• W1973485268 hasPublicationYear "2009" @default.
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