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• W1973554729 startingPage "319" @default.
• W1973554729 abstract "A modified electrode Ni(II)–BA–MWCNT-PE has been fabricated by electrodepositing nickel(II)–baicalein [Ni(II)–BA] complex on the surface of multi-wall carbon nanotube paste electrode (MWCNT-PE) in alkaline solution. The Ni(II)–BA–MWCNT-PE exhibits the characteristic of improved reversibility and enhanced current responses of the Ni(III)/Ni(II) couple compared with Ni(II)–BA–CPE. It also shows good electrocatalytic activity toward the oxidation of hydrazine. Kinetic parameters such as the electron transfer coefficient α, rate constant ks of the electrode reaction, the diffusion coefficient D of hydrazine and the catalytic rate constant kcat of the catalytic reaction are determined. Moreover, the catalytic currents present linear dependence on the concentration of hydrazine from 2.5 μM to 0.2 mM by amperometry. The detection limit and sensitivity are 0.8 μM and 69.9 μA mM−1, respectively. The modified electrode for hydrazine determination is of the property of simple preparation, good stability, fast response and high sensitivity." @default.
• W1973554729 created "2016-06-24" @default.
• W1973554729 creator A5032120514 @default.
• W1973554729 creator A5050069996 @default.
• W1973554729 date "2009-07-15" @default.
• W1973554729 modified "2023-10-13" @default.
• W1973554729 title "Ni(II)–baicalein complex modified multi-wall carbon nanotube paste electrode toward electrocatalytic oxidation of hydrazine" @default.
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• W1973554729 doi "https://doi.org/10.1016/j.talanta.2009.03.056" @default.
• W1973554729 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19559885" @default.
• W1973554729 hasPublicationYear "2009" @default.
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