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• W1973574872 abstract "S-Nitrosothiols (RSNO) are easily made by electrophilic nitrosation of thiols and are a convenient source of nitric oxide. Reaction occurs readily (in many cases) in aqueous buffer at pH 7.4 to give in addition the corresponding disulfide RSSR. If oxygen is not rigorously excluded from the solution, then the nitric oxide is converted quantitatively to nitrite ion, whereas in the absence of oxygen nitric oxide can be detected using a commercial NO-probe. Reaction, however, only occurs (apart from the photochemical pathway) if Cu2+ is present. There is often enough Cu2+ in the distilled water–buffer components to bring about reaction, but decomposition is halted if Cu2+ is complexed with EDTA. Experiments with the specific Cu+ chelator neocuproine however show that the true effective reagent is Cu+, formed by reduction of Cu2+ with thiolate ion. Kinetic experiments show that the most reactive nitrosothiols are those which can coordinate bidentately with Cu+, and there is a wide range of reactivity amongst the structures studied. Reactivity is crucially dependent on the concentrations of Cu2+ and RS–." @default.
• W1973574872 created "2016-06-24" @default.
• W1973574872 creator A5020502851 @default.
• W1973574872 date "1996-01-01" @default.
• W1973574872 modified "2023-09-30" @default.
• W1973574872 title "The mechanism of nitric oxide formation from S-nitrosothiols (thionitrites)" @default.
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• W1973574872 doi "https://doi.org/10.1039/cc9960001085" @default.
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