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• W1973575771 abstract "A porous oxohalide, Fe6Ca2(SeO3)9Cl4, has been synthesized by solid state reactions using concentrated HCl as the Cl-source. It crystallizes in the hexagonal space group P63/m with unit cell parameters a = 12.118(2) Å, c = 12.703(4) Å, Z = 2. The crystal structure is an open framework having one-dimensional channels extending along [001] that the chlorine atoms and lone pairs on Se4+ are facing. The channels in this framework structure are unusually large compared to other oxohalide compounds and also accessible to guest molecules. Water vapor sorption measurements show an uptake of 9 wt% at 293 K." @default.
• W1973575771 created "2016-06-24" @default.
• W1973575771 creator A5033919941 @default.
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• W1973575771 date "2013-01-01" @default.
• W1973575771 modified "2023-10-18" @default.
• W1973575771 title "Synthesis and crystal structure of Fe6Ca2(SeO3)9Cl4 – a porous oxohalide" @default.
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• W1973575771 doi "https://doi.org/10.1039/c3dt50952d" @default.
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