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- W1973594690 abstract "Abstract This study reports the fabrication of a highly hydrogen selective cross-linked polymer skin on a highly permeable mixed matrix membrane. Selective polymer skins were prepared by spin coating a thin layer of 6FDA-durene polymer onto ZIF-8/6FDA-durene mixed matrix membranes followed by subsequent cross-linking of the 6FDA-durene layer with ethylene diamine (EDA) vapor. Resultant membrane yielded significantly high gas pair selectivities for the separation of H2/CO2, H2/N2 and H2/CH4 of 29, 341, and 278, respectively, while also maintaining a high hydrogen permeability of 500 Barrers. The superior separation performances of this system surpass the current permeability–selectivity tradeoff limits (Robeson 2008 upper bound) for H2/CO2, H2/N2, and H2/CH4 separations. The present work elucidates the potential of fabricating a highly selective layer (thin skin) on a highly permeable membrane to obtain high permeability and high selectivity simultaneously." @default.
- W1973594690 created "2016-06-24" @default.
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- W1973594690 date "2014-10-01" @default.
- W1973594690 modified "2023-09-26" @default.
- W1973594690 title "Composite membranes with a highly selective polymer skin for hydrogen separation" @default.
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- W1973594690 doi "https://doi.org/10.1016/j.seppur.2014.08.015" @default.
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