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- W1973644967 abstract "The permeabilities and diffusivities of hydrogen in Pd100-χ-γ(Y(Gd))χAgγ alloys, where γ = 0, 5, 10, 15, 20 and 24 at.% Ag and χ (at.%) is the Y(Gd) content such that the condition γ + 3χ = 24 is satisfied, as possible diffusion membranes for hydrogen purification were measured at temperatures between 523 K and 673 K and input hydrogen pressures between 267 kPa and 667 kPa. From the permeabilities and diffusivities, the solubility constants in the alloys were calculated. The alloys Pd95-χ(Y(Gd))χAg5 with χ = 6.3 were the most permeable to hydrogen, and the permeability values were found to be about a factor of 2–2.5 higher than that in Pd-24at.%Ag alloy. The permeabilities are associated with the lattice expansion of the initial hydrogen-free alloys. Judging from the hardness measurements of the initial alloys, Pd100-χ-γ(Y(Gd))χAgγ with compositions where γ is about 15–20 at.% Ag, and χ is about 1.3–3.0 at.% Y(Gd), seem to be better materials for hydrogen diffusion membranes than Pd-(23–25)at.%Ag alloys." @default.
- W1973644967 created "2016-06-24" @default.
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- W1973644967 date "1992-07-01" @default.
- W1973644967 modified "2023-10-01" @default.
- W1973644967 title "Permeability and diffusivity of hydrogen in palladium-rich Pd-Y(Gd)-Ag ternary alloys" @default.
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- W1973644967 doi "https://doi.org/10.1016/0925-8388(92)90468-o" @default.
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