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• W1973662952 startingPage "387" @default.
• W1973662952 abstract "Amphiphilic polystyrene-b-poly(acrylic acid) (PS-b-PAA) diblock copolymers were prepared by iodide-mediated radical polymerization. Firstly, free radical polymerization of styrene was carried out with AIBN as initiater and iodoform as chain-transfer agent, giving iodine atom-ended polystyrene with controlled molecular weights. Secondly, tert-butyl acrylate (tBA) was polymerization using above obtained polystyrenes as macro-chain-transfer agents and PS-b-PtBA diblock copolymers with controlled molecular weights were obtained. Finally, amphiphilic PS-b-PAA diblock copolymers were prepared by hydrolysis of PS-b-PtBA under the acid condition. The formation of PS-b-PtBA and PS-b-PAA diblock copolymers was confirmed by the use of gel permeation chromatography and 1H NMR spectroscopy." @default.
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• W1973662952 date "2006-04-15" @default.
• W1973662952 modified "2023-09-28" @default.
• W1973662952 title "Synthesis of Amphiphilic Polystyrene-b-Poly(acrylic acid) Diblock Copolymers by Iodide-Mediated Radical Polymerization" @default.
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• W1973662952 doi "https://doi.org/10.1295/polymj.38.387" @default.
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