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- W1973670614 abstract "We report the nonlinear behavior of the CuO-concentration-dependent density (ensuremath{rho}), mean molar oxygen volume (${mathit{V}}_{0}^{mathrm{*}}$), and electrical conductivities (both ac and dc) of the ${mathrm{Bi}}_{4}$${mathrm{Sr}}_{3}$${mathrm{Ca}}_{3}$${mathrm{Cu}}_{mathit{y}}$${mathrm{O}}_{mathit{x}}$ (y=0--5) semiconducting oxide glasses. Infrared-spectroscopic data and mean molar oxygen volume (${mathit{V}}_{0}^{mathrm{*}}$) in these glasses indicate a change of [${mathrm{BiO}}_{6}$] octahedral structural unit to pyramidal [${mathrm{BiO}}_{3}$] structural unit with a change of CuO content in the glasses. However, no direct x-ray structural data of these glasses are found to show evidence of such changes. The nonlinearity is associated with the nonlinear variation of the ratio of [${mathrm{Cu}}^{+}$]/[Cu(total)] in the glasses depending on CuO concentrations, melting temperatures of the glasses, etc." @default.
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- W1973670614 date "1992-01-15" @default.
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- W1973670614 title "Nonlinear physical properties of amorphousBi4Sr3Ca3CuyOxsemiconducting oxides withybetween 0 and 5" @default.
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- W1973670614 doi "https://doi.org/10.1103/physrevb.45.1655" @default.
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