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• W1973670792 endingPage "19345" @default.
• W1973670792 startingPage "19342" @default.
• W1973670792 abstract "A new iron aziridination catalyst supported by a macrocyclic tetracarbene ligand has been synthesized. The catalyst, [(Me,EtTCPh)Fe(NCCH3)2](PF6)2, was synthesized from the tetraimidazolium precursor (Me,EtTCPh)(I)4 and characterized by NMR spectroscopy, electrospray ionization mass spectrometry, and single-crystal X-ray diffraction. This iron complex catalyzes the aziridination of electron-donating aryl azides and a wide variety of substituted aliphatic alkenes, including tetrasubstituted ones, in a “C2 + N1” addition reaction. Finally, the catalyst can be recovered and reused up to three additional times without significant reduction in yield." @default.
• W1973670792 created "2016-06-24" @default.
• W1973670792 creator A5024691248 @default.
• W1973670792 creator A5032112088 @default.
• W1973670792 date "2011-11-14" @default.
• W1973670792 modified "2023-10-03" @default.
• W1973670792 title "Synthesis of Aziridines from Alkenes and Aryl Azides with a Reusable Macrocyclic Tetracarbene Iron Catalyst" @default.
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• W1973670792 doi "https://doi.org/10.1021/ja2090965" @default.
• W1973670792 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22081884" @default.
• W1973670792 hasPublicationYear "2011" @default.
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