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- W1973683054 abstract "The technique of temperature-dependent Green's functions, as applied in a previous paper, to a molecular-field model of the ordering of ortho-${mathrm{H}}_{2}$ molecules on a rigid face-centered-cubic molecular lattice, is extended to include the effects of the interaction between the rotational motions of the molecules and the lattice vibrations on both the nature of the order-disorder transition and the value of the transition temperature for face-centered-cubic solid ortho-hydrogen. This spin-lattice coupling, resulting from the anisotropic van der Waals forces, is taken to be of the form proposed for hexagonal close-packed hydrogen. This interaction is found to lead to an additional, temperature-independent splitting of the $J=1$ rotational level. Depending on the sign and magnitude of this splitting, it is shown that either a first-order, a second-order, or no transition is obtained." @default.
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- W1973683054 date "1967-09-10" @default.
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- W1973683054 title "Orientational Order in fcc Solid Ortho-<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>H</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>: Effect of the Spin-Lattice Coupling" @default.
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- W1973683054 doi "https://doi.org/10.1103/physrev.161.493" @default.
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