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• W1973705622 startingPage "837" @default.
• W1973705622 abstract "A novel chitosan-based polymeric surfactant, DG-chitosan, was prepared via reductive N-alkylation of chitosan with 3-O-dodecyl-d-glucose in acetate buffer (pH 4.3, 0.1 M)-methanol in the presence of sodium cyanoborohydride (NaBH3CN). DG-chitosan was swelling in water, partly dissolvable in pyridine and DMF, and completely soluble in 0.1% aqueous acetic acid. 1H and 13C NMR spectroscopic analyses in 2% acetic acid-d4-methanol-d4 together with elemental analysis showed the degree of substitution was 27%. Formation of polymeric micelles was observed by use of pyrene as a fluorescent probe, and the critical aggregation concentration (CAC) of DG-chitosan was marked equal to 28.1 mg/L." @default.
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• W1973705622 date "2004-02-01" @default.
• W1973705622 modified "2023-09-23" @default.
• W1973705622 title "Synthesis of a novel polymeric surfactant by reductive N-alkylation of chitosan with 3-O-dodecyl-d-glucose" @default.
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• W1973705622 doi "https://doi.org/10.1016/j.polymer.2003.11.034" @default.
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