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- W1973707670 abstract "The electrical conductivity of γ-irradiated and unirradiated finely-divided spinels of composition (Zn2+xFe2+1-xFe3+2)O2−4 was studied in nitrogen atmosphere as a function of temperature. The results of both γ-irradiated and unirradiated ferrites with compositions x ⩽ 0.79 showed that the electrical conduction occurred by fast electron exchange amongst Fe2+ and Fe3+ ions situated on octahedral sites in the spinel lattice (hopping mechanism). For compositions x > 0.79 it was found that the transition of the charge carriers through cation vacancies is the predominant mechanism. Some breaks in the conductivity-temperature curves were found near the Curie points. The Seebeck voltage measurements showed that γ-irradiated and unirradiated spinels behave as n-type semiconductors. The effect of γ-irradiation on the conductivity, activation energy, charge carriers and the conduction mechanism is discussed." @default.
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- W1973707670 date "1988-03-01" @default.
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- W1973707670 title "Electrical conduction in γ-irradiated and unirradiated zinc-iron ferrites" @default.
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- W1973707670 doi "https://doi.org/10.1016/0040-6031(88)87236-8" @default.
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