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- W1973713375 abstract "Abstract The vaporisation of Al – Co alloys has been investigated in the temperature range of 1 201 to 1 552 K using Knudsen effusion mass spectrometry. Nine different compositions have been examined in the composition range x (Co) = 0.62 to 0.47. Al(g) and Co(g) were the vapour species observed over all the alloy samples excepting x (Co) = 0.47 over which only Al(g) could be identified. Partial pressure – temperature relations and thermodynamic activities of Co and Al were derived. The enthalpies and Gibbs free energies of formation of Al 0.5 Co 0.5 (s) at 298.15 K were obtained as Δ f H o m =− 54.9 ± 4.8 kJ mol −1 and Δ f G o m =− 51.4 ± 1.4 kJ mol −1 . This is the first time activities of Co have been determined experimentally across the B2-AlCo(s) single phase region." @default.
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- W1973713375 date "2011-10-01" @default.
- W1973713375 modified "2023-09-27" @default.
- W1973713375 title "Knudsen effusion mass spectrometric studies of the B2 phase in the Al – Co system" @default.
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- W1973713375 doi "https://doi.org/10.3139/146.110578" @default.
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