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• W1973752457 abstract "Rhodium complexes with the planar chiral phosphinoferrocenyl thioether ligands [Rh(P,SR)(diene)X] (R = Me, But, Ph, Bn, diene is cyclooctadiene (COD) or norbornadiene (NBD), X = Cl, BF4) catalyze hydrogenation of ketones, imines, and heteroaromatic compounds; in the case of acetophenone, the enantioselectivity reached 60% ee. Similar iridium complexes demonstrate a good activity in the hydrogenation of imines, the maximal enantioselectivity in the case of N-phenyl-N-(1-phenylethylidene)amine was about 40% ee." @default.
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• W1973752457 date "2013-03-01" @default.
• W1973752457 modified "2023-10-16" @default.
• W1973752457 title "Iridium and rhodium complexes with the planar chiral thioether ligands in asymmetric hydrogenation of ketones and imines" @default.
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• W1973752457 doi "https://doi.org/10.1007/s11172-013-0102-5" @default.
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