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- W1973758439 abstract "Über Schmelzreaktionen in einer Stickstoffatmosphäre wurden folgende Sulfide dargestellt: Rb2Mn3S4, Cs2Mn3S4, Rb2Co3S4 und Cs2Co3S4. Strukturuntersuchungen an Einkristallen von Cs2Mn3S4 führten zu der Raumgruppe Ibam–D mit Z = 4. Die Anordnung der Atome ergibt eine Schichtenstruktur, in der alternierende Mangan- und Alkalimetallschichten jeweils durch Schwefellagen getrennt sind. Untersuchungen an pulverförmigen Präparaten ergaben für die übrigen Sulfide einen isotypen Aufbau. The compounds Rb2Mn3S4, Cs2Mn3S4, Rb2Co3S4 and Cs2Co3S4 were prepared by melting reactions in a nitrogen atmosphere. X-ray investigations of Cs2Mn3S4 single crystals lead to the space group Ibam–D Z = 4. The manganese- as well as the alkalimetal-atoms are arranged in layers which are separated by sulphur layers. The other compounds have an analogous structure. This could be shown by powder diffraction investigations." @default.
- W1973758439 created "2016-06-24" @default.
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- W1973758439 date "1972-05-01" @default.
- W1973758439 modified "2023-10-14" @default.
- W1973758439 title "�ber Thiomanganate und -cobaltate der schweren Alkalimetalle: Rb2Mn3S4, Cs2Mn3S4, Rb2Co3S4, Cs2Co3S4" @default.
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- W1973758439 doi "https://doi.org/10.1002/zaac.19723900102" @default.
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