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- W1973776937 abstract "New (Ce0.72Cu0.28)100−x−yAlx(Ga,Zn)y bulk metallic glasses (BMGs) with ultra-low glass transition temperatures and large supercooled liquid regions (ΔTx) were developed. The addition of Al element into Ce–Cu alloys improves significantly glass formation ability (GFA) of the alloys and the maximum value of ΔTx is 63 K. The lowest glass transition temperature (Tg) was found in the (Ce0.72Cu0.28)97.5Al2.5 BMG alloy and the value is 326 K. The addition of Ga and Zn elements into Ce–Cu–Al alloys has no obvious role in the decrease of Tg. However, Tg has a close relation to Ce content and decreases with increasing Ce content. The activation energies of the glass transition are 136 kJ·mol−1 for the (Ce0.72Cu0.28)97.5Al2.5 glassy alloy and 145 kJ·mol−1 for the Ce62.5Cu15Al12.5Ni10 glassy alloys, respectively. The successful fabrication of Ce-based BMGs with ultra-low Tg and large ΔTx can further extend the potential application of bulk metallic glasses in some special industry fields." @default.
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- W1973776937 date "2005-01-01" @default.
- W1973776937 modified "2023-10-03" @default.
- W1973776937 title "Ultra-Low Glass Transition Temperatures in Ce-Based Bulk Metallic Glasses" @default.
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- W1973776937 doi "https://doi.org/10.2320/matertrans.46.1857" @default.
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