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- W1973798579 abstract "Surface enhanced Raman optical activity spectroscopy (SEROA) of chiral molecules has proved much more challenging than conventional surface enhanced Raman spectroscopy (SERS). To further understand this, we calculated the “chemical effects” of molecule−metal binding in SEROA. The SEROA peaks’ signs and magnitudes are very sensitive to molecule−metal orientation; thus, SEROA from different molecules may cancel in ensemble measurements. We suggest that future SEROA experiments use ordered monolayers of chiral molecules to minimize orientational effects." @default.
- W1973798579 created "2016-06-24" @default.
- W1973798579 creator A5016283866 @default.
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- W1973798579 date "2009-05-06" @default.
- W1973798579 modified "2023-10-10" @default.
- W1973798579 title "Molecule−Surface Orientational Averaging in Surface Enhanced Raman Optical Activity Spectroscopy" @default.
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- W1973798579 doi "https://doi.org/10.1021/jp9025514" @default.
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