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- W1973833159 abstract "We study the diffusion of small guest particles of different sizes in a host fluid at liquid densities using molecular dynamics simulations. We observe an enhancement of the diffusivity of guest particles for a size related to the structure of the void space of the host fluid, analogous to the ``levitation effect'' observed for guest diffusion in porous solids. Friction and activation energy are found to be minimum for the guest size with maximum self-diffusivity. Wavelength dependent self-diffusivity indicates a monotonic and oscillatory dependence on wave number $k$ for anomalous and linear regimes, respectively. These are associated with single and bi-exponential decay of the incoherent intermediate scattering function." @default.
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- W1973833159 date "2005-09-16" @default.
- W1973833159 modified "2023-10-17" @default.
- W1973833159 title "Diffusion maximum as a function of size in dense liquids" @default.
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- W1973833159 doi "https://doi.org/10.1103/physreve.72.030202" @default.
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