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- W1973842026 abstract "Abstract The outer-sphere interaction between the Co(CN)6 3- anion with the two protonated forms of DABCO (1,4-diazabicyclo[2.2.2]octane) was investigated by a spectrophotometric titration method. The resulting outer-sphere stability constant for the diprotonated DABCOH2 2+ cation was determined as log KOS = 2.53 ± 0.01, compared to the value of 2.77 ± 0.12 obtained using conventional potentiometric titration results. Absorption changes were very small; however, good reproducible results were obtained for the higher charged diprotonated cation interaction and the method may have general application." @default.
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- W1973842026 date "1994-07-01" @default.
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- W1973842026 title "A spectrophotometric method for the quantification of outer-sphere coordination: A bicyclic ammonium cation with the hexacyanocobaltate(III) anion" @default.
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- W1973842026 doi "https://doi.org/10.1080/10610279408034924" @default.
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