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- W1973843208 abstract "Abstract The complex Cp′Mn(CO) 3 (Cp′=η 5 -C 5 H 4 –CH 3 ) reacts with P(C 6 H 5 ) 2 H in THF to give Cp′(CO) 2 MnPPh 2 H (Ph=phenyl) ( 1 ), by substitution of one CO ligand. The reaction of 1 with CH 3 COCl and CH 3 S(O) 2 Cl in the presence of triethylamine occurs under electrophilic substitution on the diphenylphosphane ligand yielding the acetyl and sulfonylphosphane complexes of manganese(I) Cp′(CO) 2 MnPPh 2 COCH 3 ( 2 ) and Cp′(CO) 2 MnPPh 2 S(O) 2 CH 3 ( 3 ). The complex stabilization of these molecules, which are hitherto unknown in the free state, is only accomplished by blocking the free electron pair on phosphorus by coordination. The new complexes 1 , 2 and 3 were analyzed by IR, 1 H and 31 P NMR spectroscopy and their similar structures are discussed." @default.
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- W1973843208 date "1999-05-01" @default.
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- W1973843208 title "Reactions of Cp′(CO)2MnPPh2H with CH3COCl and CH3S(O)2Cl in THF/triethylamine: evidence of the first complex stabilization of a phosphorus homolog of the sulfonamides" @default.
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- W1973843208 doi "https://doi.org/10.1016/s0020-1693(99)00015-8" @default.
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