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• W1973854414 startingPage "4186" @default.
• W1973854414 abstract "Novel metal complexes M(hfac)2(PyBTM)2 [M = CuII, ZnII; hfac = hexafluoroacetylacetonato; PyBTM = (3,5-dichloro-4-pyridyl)bis(2,4,6-trichlorophenyl)methyl radical] were prepared. Both hexacoordinated complexes had elongated octahedral geometry, in which two PyBTM molecules coordinated at the equatorial positions in CuII(hfac)2(PyBTM)2 but at the axial positions in ZnII(hfac)2(PyBTM)2. Magnetic studies revealed an intramolecular ferromagnetic exchange interaction between the spins on PyBTM and CuII (JCu–R/kB = 47 K) based on the orthogonality of the two spin orbitals." @default.
• W1973854414 created "2016-06-24" @default.
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• W1973854414 date "2015-04-17" @default.
• W1973854414 modified "2023-10-16" @default.
• W1973854414 title "Intramolecular Ferromagnetic Radical–Cu^II Coupling in a Cu^II Complex Ligated with Pyridyl-Substituted Triarylmethyl Radicals" @default.
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• W1973854414 doi "https://doi.org/10.1021/acs.inorgchem.5b00499" @default.
• W1973854414 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25884727" @default.
• W1973854414 hasPublicationYear "2015" @default.
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