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• W1973909172 abstract "Squaraines are a class of organic fluorophores that possess unique photophysical properties, including strong near-infrared absorption and emission. The synthesis of many squaraines involves the condensation of an electron-rich aromatic ring with squaric acid. These reactions are generally refluxed overnight in a benzene–butanol solvent mixture. Reported herein are modifications to the synthesis of a squaraine dye that allowed the experiment to be performed in an undergraduate laboratory setting. The desired compound was formed after a 2-h reflux, using toluene as a co-solvent rather than the more toxic benzene. Moreover, the photophysical properties of the synthesized squaraine compound were analyzed in a separate laboratory period and led to important pedagogical opportunities about the absorption and fluorescence of organic compounds." @default.
• W1973909172 created "2016-06-24" @default.
• W1973909172 creator A5072237449 @default.
• W1973909172 creator A5091513628 @default.
• W1973909172 date "2012-07-26" @default.
• W1973909172 modified "2023-09-26" @default.
• W1973909172 title "Synthesis of a Near-Infrared Emitting Squaraine Dye in an Undergraduate Organic Laboratory" @default.
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• W1973909172 doi "https://doi.org/10.1021/ed300187d" @default.
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